4 结论
采用熔融玻璃结合循环加热的方法,研究了Ni80B20合金熔体深过冷快速凝固中的相竞争规律。主要结论如下:
(1)组织演化表明,当Ni80B20合金过冷度大180K时,在竞争形核中Ni3B作为初生相从熔体析出。反之,Ni(α)作为初生相从熔体析出
(2) 当Ni80B20合金过冷度小于180K时,Ni(α)的孕育时间短,Ni(α)首先形核,且由于Ni(α)的生长速度相对较大,Ni(α)呈枝晶形态;过冷度大于180K时,Ni3B的孕育时间短,Ni3B作为初生相,且Ni3B的生长速度相对较小,Ni3B呈球状。形核很大程度上决定相形成的竞争,而生长很大程度上决定相形态的竞争。
参考文献
[1] G R Wood, A G Waltons. Homogeneous nucleation kinetics of ice from water [J]. Journal of Applied Physics, 1970,41:3027.
[2] J H Perepezko. Nucleation in Undercooled Liquids [J]. Materials Science and Engineering, 1984, 65:125-135.
[3] J H Perepezko, J S Paik. Thermodynamic properties of undercooled liquid metals [J]. Journal of Non-Crystalline Solids, 1984, 61-62: 113.
[4] G Shao, P Tsakiropoulos. Prediction of phase selection in rapid solidification using time dependent nucleation theory Acta [J]. Metall. Mater, 1994,42:2937.
[5] D Turnbull. On the relation between crystallization rate and liquid structure [J]. Physical Chemistry, 1962, 66(4): 609.
[6] W Kurz, D J Fisher. Fundamentals of solidication [M]. Switzerlan: Trans Pub.Ltd,1998,1-3
[7] Yanqing Su, Chang Liu, Xinzhong Li, et al. Microstructure selection during the directionally peritectic solidification of Ti–Al binary system [J]. Intermetallics, 2005, 13: 267.
[8] Jingjie Guo, Xinzhong Li, Yanqing Su, et al. Microstructure selection during the directionally peritectic solidification of Ti–Al binary system [J]. Intermetallics, 2005, 13:275.
[9] N Wang, B Wei. Rapid crystallization and growth mechanism of highly undercooled Ag-Cu-Ge ternary alloy [J]. Journal of Crystal Growth, 2003, 247:576-586
[10] N Wang, B Wei. Rapid solidification behaviour of Ag–Cu–Ge ternary eutectic alloy [J]. Materials Science and Engineering, 2001, 307A: 80.
[11] W J Yao, X J Han, B Wei. Microstructural evolution during containerless rapid solidification of Ni–Mo eutectic alloys [J]. Journal of Alloys and Compounds, 2003, 348: 88.
[12] 陈豫增,杨根仓,王猛,等. 深过冷Ni80.3B19.7合金的再辉和非规则共晶的形成 [J]. 材料研究学报,2005 ,19(4):382.
[13] Y Z Chen, F Liu, G C Yang, et al. Discussion on nucleation mechanism of undercooled Ni80.3B19.7 melts [J]. Journal of Alloys and Compounds, 2007,439:166-170.